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UniversidaddeCádiz
Instituto de Investigación Vitivinícola y Agroalimentaria IVAGRO

UniversidaddeCádiz

Instituto de Investigación Vitivinícola y Agroalimentaria IVAGRO
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Acetonitrile complexRemove (1)

 

N -Alkylation of organonitrogen compounds catalyzed by methylene-linked bis-NHC half-sandwich ruthenium complexes

N -Alkylation of organonitrogen compounds catalyzed by methylene-linked bis-NHC half-sandwich ruthenium complexes

Posted May 18, 2022

DOI 10.1039/D1OB02214H KEYWORDS Acetonitrile complex; N-Alkylation ABSTRACT An efficient ruthenium-catalyzed N-alkylation of amines, amides and sulfonamides has been developed employing novel pentamethylcyclopentadienylruthenium(II) complexes bearing the methylene linked bis(NHC) ligand bis(3-methylimidazol-2-ylidene)methane. The acetonitrile complex 2 has proven particularly effective with a broad range of substrates with low catalyst loading (0.1–2.5 mol%) and high functional group tolerance under mild conditions. A […]